Introduction: Searching for Reproducibility

This Ciber Lab was looking for ways to overcome limitations of volume and size, and to produce and reproduce nano-optical images more easily and at larger scales. The novelty they proposed was to move away from a process of fabrication that structurally bound image and material, to one that divided the material and the process. This would open the door to producing both small batches and larger images.

They developed a two-step approach (Fig. 1): 1) the production of a generic pixelated nanosubstrate, and 2) the accompanying processes for adding information onto/into it through an intensity control layer (ICL) or mask, which would individually control the luminance of the underlying RGB pixelated layer to make possible fully colourful images. Together these make up the lab’s central scientific contributions in terms of their retooling of the processes used for the production of nano-optical images and structures, which they to came to call nano media.


Fig. 1 Schematic of the two-step approach developed by the Ciber Lab.

Samples in petri dishes at the Ciber Lab
Early sample of nano media, produced by the Ciber Lab in 2014

Image credit : Simon Fraser University

Making Nano Media: Step 1

The generic nanosubstrate is made up of approximately one billion nanostructures in a square centimetre. These nano-hole arrays (NHAs) are produced using varying techniques, such as electron beam lithography (EBL) or focused ion beam (FIB) milling. Importantly, this system of NHAs is designed as a pixelated pattern using three (red-green-blue) or four (RGB + infrared) sub-pixels (see gallery). These are determined by the particular size and shape of the nanostructure so that, in the case of the information in the visible spectrum, the designated colour can be seen at a specific viewing angle.

Resolution meanwhile is defined based on the size and density of the NHAs and can differ according to the design of the pixelation pattern (e.g. bands or squares) and the materials used. In principle, a variety of materials can be pixelated in such a way, including metals, polymers, paper, tissue/fabric, or glass, and then coated through a process of metallization with silver, aluminum, or gold to brighten the colours (making use of the particular interactions of light with metal, or plasmonics).

Colourized example of a pixel pattern substrate.
Image of pixel pattern substrate produced with scanning electron microscope (SEM) at a scale of 100µm.
Nanosubstrate and the imprinted structural pixels. a. SEM image of the fabricated nanosubstrate on quartz showing R, G, B, and IR sub-pixels.
Each sub-pixel is 10µm × 10µm in size. b. 45° SEM images of the nanocone arrays imprinted from the nanosubstrate using, shown at a scale of 1µm. [J6, P2].

Image credit : Ciber Lab

Making Nano Media: Step 2

A nano-optical substrate is not limited to the production of red, green, and blue colours. The idea of a generic pixelated canvas means that it can function much like a LCD screen. Rather than being electrically activated however, the pixels can be tuned through various mechanical or chemical processes to produce specific colours across the visible spectrum. The various methods for “tuning,” or patterning, the substrate—inscription, etching, exposing, writing, layering, molding, stamping, etc.—remediate the processes and logics of analog modes of image-making onto a new material, each coming with particular production or reproduction dis/advantages, and each resulting in a different quality of image.

In our projects, the image—including their colours, visibility angles, and brightness—had to be defined between the artists and scientists. Then, the Ciber Lab fabricated a master stamp according to this established design for each colour image. Then, secondary stamps with generic pixel bands (in R, G, B) were replicated from the master stamp and “tuned” using micro-scale patterning techniques, including optical lithography, photographic recording, inkjet printing, or laser writing (chosen based on the required resolution and colour levels of the final image produced).


Fig. 1 Schematic process of printing structural colour images from a reusable generic nanosubstrate. a. Schematic diagram of nanosubstrate containing red (R), green (G), blue (B), and infrared (IR) subpixels. The features in the diagram are tinted with colours to assist recognition of the subpixels. b. The nanosubstrate is covered by a flat mask layer composed of positive-tone photoresist. c. The mask layer is exposed with a pattern by laser writer. d. The development of the mask layer opens apertures to allow access to the red and green subpixels. e. Nanoimprint lithography using the masked nanosubstrate as stamp to imprint structural colour images. The nanosubstrate is cleaned and ready for printing a new image [J6, P2].

Figure 1 shows one typical process where a secondary stamp is patterned using optical lithography to define a specific structural colour pattern. The generic substrate is first coated with a photosensitive material, which can be selectively removed using optical lithography. Optical lithography can be done using either UV laser writing or UV exposure through a binary photomask. With exposure followed by chemical development, here the nano-structures were selectively opened and replicated onto another separate substrate which became the final colourful nano media artefact.

Inspiration

As the Lab’s techniques of “addition” developed or shifted, a variety of terms were floated about in the team to describe this nano-optical visual technology: nanographs, nanophotos, nanoprints, nanofilm, nano-etchings. The familiar ring to these names was no coincidence as the material process of adding an image to a substrate follow the same logic as analog methods for producing images, and these processes did serve as inspirations for the scientific team.


Fig. 1 Inspiration drawn from early 20th century techniques, like the Dufay colour film or autochromes.

The histories of printed pictures, photomechanical processes, and screen technologies allow us to see the many ways that nano-optical image-making can be mapped onto the technical histories of art and media production. Processes from the early 20th century like Dufay colour film or autochromes (Fig. 1), for example, used a similar principle that relied on a generic pixelated pattern made up of the additive primaries—red, green, blue—and a coating system (in these cases, black-and-white) for modulating the colours as desired. Later, photographic emulsions with separated coloured layers became the dominant colour recording medium. The scales and materials have changed, but the basic principles of how to work with light to fix colours and pictures has remained. And this without even yet considering the infrared subpixel, which reminds us that a nano-optical material can also store information invisibly, ultimately encoding information through a system of grooves, pits, and holes much like it has been done in punched card systems or optical discs.

Fabrication at the Ciber Lab

Here is documentation of the fabrication process of Nano Media at Ciber Lab.

Fabrication of Nano Media using inkjet printing. Micron- scaled dots are selectively deposited onto the nanosubstrates to form into desired colour images.
The 4D Labs cleanroom facility at Simon Fraser University. The particles in the air of a cleanroom must be kept at a very low level. All users must wear gowns to minimize particles released from humans into the lab.
Mask aligner photolithography equipment inside 4D Labs cleanroom. A nanosubstrate can be patterned optically using the mask aligner.
Dr. Hao Jiang operating a mask aligner under microscope to match the orientation of the nanosubstrate with the equipment axes.
A plasmonic colour pattern fabricated using electron beam lithography, nanoimprinting, and physical vapor deposition.
Dr. Jiang holding a metalized nanosubstrate, which reflects bright colours at certain lighting and viewing angles.
A physical vapor deposition to deposit thin metallic film on the surface of nanostructured polymer surface.
Dr. Jiang operating the physical vapor deposition machine.
Electron beam lithography equipment inside 4D Labs. The patterning accuracy is in nanoscale.
Dr. Jiang operating the electron beam lithography equipment.
A fumehood chemical working bench inside 4D Labs, dedicated for processing organic chemicals, which are used to process Nano Media.
Optical microscopes inside 4D Labs for examining the manufactured Nano Media.
Dr. Jiang operating the optical microscope to examine the Nano Media.
A spin coater inside 4D Labs, which can deposit a uniform thin film of photoresist layer on top of a wafer.
A fumehood chemical working bench inside 4D Labs, dedicated for processing organic chemicals, which are used to process Nano Media.
Dr. Jiang working on the custom-built optical setup to examine the Nano Media.
Dr. Bozena Kaminska and the scientific team at Simon Fraser University.

Image credit : Simon Fraser University

Hello. Welcome into Project Nanoverse. Nice to meet you!